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liquefied petroleum gas : ウィキペディア英語版
liquefied petroleum gas

Liquefied petroleum gas or liquid petroleum gas (LPG or LP gas), also referred to as simply propane or butane, are flammable mixtures of hydrocarbon gases used as fuel in heating appliances, cooking equipment, and vehicles.
It is increasingly used as an aerosol propellant and a refrigerant, replacing chlorofluorocarbons in an effort to reduce damage to the ozone layer. When specifically used as a vehicle fuel it is often referred to as autogas.
Varieties of LPG bought and sold include mixes that are primarily propane (), primarily butane () and, most commonly, mixes including both propane and butane. In the northern hemisphere winter, the mixes contain more propane, while in summer, they contain more butane.〔(【引用サイトリンク】title=Analysis of seasonal mixtures - Propane-butane Fuel Mixture (Summer, Winter) )〕 In the United States, primarily two grades of LPG are sold: commercial propane and HD-5. These specifications are published by the Gas Processors Association (GPA)〔(【引用サイトリンク】url=https://www.gpaglobal.org/publications/view/id/36/ )〕 and the American Society of Testing and Materials (ASTM).〔(【引用サイトリンク】url=http://www.astm.org/Standards/D1835.htm )〕 Propane/butane blends are also listed in these specifications.
Propylene, butylenes and various other hydrocarbons are usually also present in small concentrations. HD-5 limits the amount of propylene that can be placed in LPG to 5%, and is utilized as an autogas specification. A powerful odorant, ethanethiol, is added so that leaks can be detected easily. The internationally recognized European Standard is EN 589. In the United States, tetrahydrothiophene (thiophane) or amyl mercaptan are also approved odorants, although neither is currently being utilized.
LPG is prepared by refining petroleum or "wet" natural gas, and is almost entirely derived from fossil fuel sources, being manufactured during the refining of petroleum (crude oil), or extracted from petroleum or natural gas streams as they emerge from the ground. It was first produced in 1910 by Dr. Walter Snelling, and the first commercial products appeared in 1912. It currently provides about 3% of all energy consumed, and burns relatively cleanly with no soot and very few sulfur emissions. As it is a gas, it does not pose ground or water pollution hazards, but it can cause air pollution. LPG has a typical specific calorific value of 46.1 MJ/kg compared with 42.5 MJ/kg for fuel oil and 43.5 MJ/kg for premium grade petrol (gasoline). However, its energy density per volume unit of 26 MJ/L is lower than either that of petrol or fuel oil, as its relative density is lower (about 0.5–0.58 kg/L, compared to 0.71–0.77 kg/L for gasoline).
As its boiling point is below room temperature, LPG will evaporate quickly at normal temperatures and pressures and is usually supplied in pressurised steel vessels. They are typically filled to 80–85% of their capacity to allow for thermal expansion of the contained liquid. The ratio between the volumes of the vaporized gas and the liquefied gas varies depending on composition, pressure, and temperature, but is typically around 250:1. The pressure at which LPG becomes liquid, called its vapour pressure, likewise varies depending on composition and temperature; for example, it is approximately for pure butane at , and approximately for pure propane at . LPG is heavier than air, unlike natural gas, and thus will flow along floors and tend to settle in low spots, such as basements. There are two main dangers from this. The first is a possible explosion if the mixture of LPG and air is within the explosive limits and there is an ignition source. The second is suffocation due to LPG displacing air, causing a decrease in oxygen concentration.
==Uses==
LPG has a very wide variety of uses, mainly used for cylinders across many different markets as an efficient fuel container in the agricultural, recreation, hospitality, calefaction, construction, sailing and fishing sectors. It can serve as fuel for cooking, central heating and to water heating and is a particularly cost-effective and efficient way to heat off-grid homes.
In the safety font LPG cylinders must be updated to new standards in safety and user experience, giving a huge contribution for domestic usage.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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